Feldspar Days: From the Earth's crust up high in the sky

20.05.2025

Feldspar - the most common mineral in the Earth's crust - is also found up high in the sky as mineral dust, where it supposedly plays an important role regarding ice nucleation and clouds. From 24th to 25th of April this year researchers from all over Europe gathered at our faculty to discuss the different approaches of addressing ice nucleation on feldspar surfaces.

Feldspar is the most common mineral in the Earth's crust, constituting about 50% of its volume. But Feldspar not only paves the ground, it is also found high up in the sky, where it forms about 10% of the airborne mineral dust and supposedly plays an important role in the formation of ice in tropospheric clouds.

Which role and how important it is, was topic of the Feldspar Days in April 2025 at the Department of Lithospheric Research in Vienna. The petrology working group at the department is involved in cloud microphysics studies on ice nucleation on feldspar. "What started as a bilateral FWF-DFG project between the Karlsruhe Institute of Technology and UNIVIE has become a multilateral, highly interdisciplinary international group sharing the aim to unravel the mechanisms underlying the extraordinary ice-nucleating activity of alkali feldspar", says Rainer Abart, head of the Petrology group and Dean of the Faculty of Earth Sciences, Geography and Astronomy.

Aim to unravel the mechanisms underlying the extraordinary ice-nucleating activity of alkali feldspar

From 24th to 25th April, 25 researchers from all over Europe gathered at our faculty to discuss the different approaches of addressing ice nucleation on feldspar surfaces, including targeted freezing experiments done at the Department of Lithospheric Research and at the Karlsruhe Institute of Technology (KIT), Non Contact Atomic Force Microscopy done at TU Vienna and at University of Bielefeld which delivers atomic scale information on the adsorption of H2O molecules on feldspar surfaces, synchrotron experiments at the Hamburg Synchrotron Facility that allow for monitoring ice nucleation in real time, and atomistic modelling, which is performed at the Faculty of Physics, UNIVIE, at TU Vienna, and at the University of Helsinki.

Alkali feldspar aerosol particles raise ice nucleation temperatures

In the absence of aerosols, micrometer-sized water droplets suspended in air can be supercooled to about -37°C before homogeneous ice nucleation sets in. In the presence of aerosols, the suspended droplets freeze anywhere between 0◦C and -37◦C. Aerosol particles of alkali feldspar, a subgroup of the feldspar minerals, are particularly efficient in raising ice nucleation temperatures.

Ice formation influences the physical properties of clouds

Ice formation influences the physical properties of clouds, including, among others, their reflectivity, with implications for the Earth’s radiation balance and climate. Moreover, ice particles serve as a substrate for the adsorption of trace gases and thus influence atmospheric chemistry. It is therefore of considerable interest to understand why alkali feldspar aerosol particles exhibit their extraordinary ice-nucleating properties.

Another example of how the diversity in our faculty can lead to interesting new avenues of research


"Hosting the highly interdisciplinary Feldspar&Ice community at our faculty is another example of how the diversity in our faculty can lead to interesting new avenues of research", says Abart.

Feldspar is found in the Earth's crust, but also high up in the sky in form of mineral dust with effect on ice nucleation temperatures.

Picture: Feldspar cleavage plate on a silver block that can be cooled with liquid nitrogen and counter heated for precise temperature control. Arrays of about 100 droplets (7 nanoliter) of ultrapure water are applied on the feldspar plate using an automated droplet dispenser and then subjected to a cooling ramp. The freezing of individual droplets is monitored by an infrared camera based on the latent heat of freezing emitted during the freezing event. (C) M. Hagen

From the fraction of frozen droplets as a function of temperature, the ice nucleation activity of specific feldspar plates is extracted. Kiselev et al. (2021) Atmos. Chem. Phys., 21, 11801–11814

Scanning Electron Microscope (SEM) image of natural alkali feldspar with nanoporosity due to enhanced dissolution along misfit dislocations between exsolved Na-rich and K-rich lamellae. The pores may serve as preferred ice-nucleation sites. (C) Gerlinde Habler

Schematic illustration of the SiO4 (red circles) and AlO4 (blue circles) – tetrahedral framework of Al-Si ordered alkali feldspar (microcline). Microcline is particularly ice nucleation active, which may be due to its ordered Al-Si distribution serving as a template for transforming liquid water into ice crystals. It is still a matter of debate whether the extraordinary ice nucleation activity of alkali feldspar is due to its specific surface topography or to its atomic structure.