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Calibration for REE separation (micro-columns)

Sm-Nd mineral dating and Nd isotope geochemistry by ID-TIMS

The Sm-Nd method is a vital isotope analytical tool to approach both petrogenetic as well as geochronological questions. However, precise and accurate Sm-Nd isotope analysis for low-concentration material is only possible by ID-TIMS.
Fields of interest
Over the past 15 years, in our lab samples were analyzed mainly from the Alps and the Himalaya-Tibet orogenic belts, but also from other parts of the world (Mediterranean area, Africa, S-America).

  • Epsilon (ε) Nd values and Sm-Nd model ages (DM, Depleted Mantle model ages) are used to discriminate whole-rock protolith materials which are derived from more juvenile or from long-term LILE depleted vs enriched sources. In addition, and mostly in combination with mineral dating, DM model ages from whole rocks are used to estimate a “mean crustal residence time” for rocks of the continental crust (clastic sediments or their metamorphic derivates: schists, gneisses).

  • Our main interest, however, is focused on mineral dating. The most important prerequisite for successful Sm-Nd mineral dating are ultrapure mineral separates. Depending on Nd concentration, sample sizes of some 10 - 100 mg are generally required (hence time-consuming hand-picking under the binocular microscope is inevitable!). To improve sample purity and to eliminate optically undetected micro-inclusions, acid leaching experiments (mainly for garnet) are also successfully performed.

  • Garnet has variable, but generally high Sm/Nd ratios if compared with other minerals (the highest Sm/Nd ratios measured so far are > 16), and therefore it yields important time information in metamorphic rocks, but also in (meta-)igneous rocks. Because of its prominent importance for P-T-d estimation, Sm-Nd data from this mineral have been frequently determined  in order to link P-T-d and geochronological information directly (i.e., for one and the same material). In addition, garnet often shows conspicuous grain-internal trace element zonation resulting in strong variation of Sm/Nd, thus allowing “internal garnet isochrons” to be calculated. In our laboratory, Sm-Nd garnet analyses have been performed during the past fifteen years for a range of P-T conditions and on various lithologies (metabasites, metapelites, meta-pegmatites, dykes), with emphasis on the Eastern Alps.

  • Despite the well-known low-fractionation behavior of REE, the apparent “spread” in Sm/Nd of the different minerals pertaining to one and the same assemblage - most importantly major and trace mineral phases - is generally sufficient to allow internal time resolution to be made. The following materials have been analyzed:

  • Plagioclase-clinopyroxene (+ wr, ± orthopyroxene) pairs from gabbros (magmatic crystallsation age)

  • Garnet-omphacite (+ zoisite, + amphibole, + phengite) pairs from eclogite (high-P age)
A: Kyanite-free, low-Mg eclogite (plane polarized light) from Gertrusk, Saualpe, used for Sm-Nd mineral dating. Amp = amphibole, Sym = symplectite, Grt = garnet, Rt = rutile, Omp = omphacite, Qtz = quartz. B: Example Sm-Nd dating of high-P metamorphism: Sm-Nd mineral isochron age for eclogite from the Saualpe top (Gertrusk), interpreted to date the final high-P stage (P c. 2.2±0.2 GPa at T = 630-740 °C).

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    • Garnet-feldspar (+ wr, + mica, + staurolite) pairs from schists, paragneisses (metamorphic crystallization)
    Example Sm-Nd dating of a metamorphic high-PT stage: Multimineral–whole rock isochron age of a high-P metapelite from the Saualpe (host rock of eclogite at the eclogite type-locality); the pyrope-rich garnet is interpreted to date the final high-P stage (at P c. 2.0±0.2 GPa, T = 685 °C).

       

      • Garnet-feldspar (+ wr, + mica, + staurolite) pairs from schists, paragneisses (metamorphic crystallization)

      • Garnet-feldspar (wr) pairs from (meta-)pegmatite / meta-granite, combined with precise ID-TIMS analysis of the co-existing high-REE accessory phases monazite, apatite, xenotime, titanite (and zircon) (emplacement age).


      Contact:
      Martin Thöni, Monika Horschinegg

      Schrift:

      Kontakt
      Department of Lithospheric Research
      University of Vienna
      Althanstraße 14
      1090 Vienna

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